Criteria of thermodynamic similarity: sources and forecast at the molecular level

Abstract

One more control factor of a new one-parameter family of equations has been added to a number of known thermodynamic similarity criteria. Its relation to the characteristics of the molecular level is established. The results obtained earlier at the atomic-molecular level of modeling objects and interactions make it possible to predict the values of a number of criteria on the basis of minimal information about molecules.

Keywords

• model of interacting centers
• similarity criteria
• control factor
• spherical shell model
• object rigidity
• critical compressibility factor
• prediction of similarity criteria