Influence of the angle of the two paraquat groups in the central benzene of the bisparaquat derivatives on complexation of a crown ether with bisparaquat derivatives(双百草枯衍生物中以苯为中心的两个百草枯基团的夹角对冠醚与双百草枯络合的影响)

Affiliations

YEYu-yuan(叶余原): Department of Chemistry, Taizhou University, Linhai 317000, Zhejiang Province, China(台州学院化学系，浙江　临海　317000)
ZHENGRen-hua(郑人华): Department of Chemistry, Taizhou University, Linhai 317000, Zhejiang Province, China(台州学院化学系，浙江　临海　317000)
ZHONGAi-guo(钟爱国): Department of Chemistry, Taizhou University, Linhai 317000, Zhejiang Province, China(台州学院化学系，浙江　临海　317000)
HEBing-jing(何冰晶): Department of Chemistry, Taizhou University, Linhai 317000, Zhejiang Province, China(台州学院化学系，浙江　临海　317000)
CHENRen-er(陈仁尔): Department of Chemistry, Taizhou University, Linhai 317000, Zhejiang Province, China(台州学院化学系，浙江　临海　317000)
ZHOUQi-zhong(周其忠)
JIANGHuajiang(蒋华江)

Abstract

设计并合成了一种新颖的冠醚5和3种有着不同夹角（A180、A120和A60）的双百草枯衍生物.双百草枯衍生物中以苯为中心的两个百草枯基团间的夹角的作用表现为：冠醚5对类双百草枯的络合有着显著的影响.量子化学计算也论证了这一结果.冠醚5对上述3种类双百草枯有着选择性识别作用.

ISSN: 1008-9497 (Print)
Publisher: Zhejiang University Press
Country of publisher: China
LCC subjects: Science: Mathematics: Instruments and machines: Electronic computers. Computer science; Science: Physics
Website: https://www.zjujournals.com/sci/EN/1008-9497/home.shtml