IUCrData (Jan 2016)

Bis[μ-2-(phenylsulfanyl)anilido-κ2N:N]bis[bis(tetrahydrofuran-κO)lithium]

  • Velabo Mdluli,
  • James A. Golen,
  • David R. Manke

DOI
https://doi.org/10.1107/S2414314616001309
Journal volume & issue
Vol. 1, no. 1
p. x160130

Abstract

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The title compound, [Li2(C12H10NS)2(C4H8O)4], exists as a dimer in the solid state, with a central four-membered Li2N2 ring that is planar by crystallographic inversion symmetry. The Li atoms are bridged by the N atoms of two anilide ligands, and each Li atom is coordinated by two O atoms from tetrahydrofuran ligands, resulting in a distorted tetrahedral N2O2 environment. One of the tetrahydrofuran rings is disordered over two sets of sites in a 0.665 (16):0.335 (6) ratio.

Keywords