Nanomaterials (Jan 2022)

Nanoarchitectonics for High Adsorption Capacity Carboxymethyl Cellulose Nanofibrils-Based Adsorbents for Efficient Cu<sup>2+</sup> Removal

  • Rongrong Si,
  • Yehong Chen,
  • Daiqi Wang,
  • Dongmei Yu,
  • Qijun Ding,
  • Ronggang Li,
  • Chaojun Wu

DOI
https://doi.org/10.3390/nano12010160
Journal volume & issue
Vol. 12, no. 1
p. 160

Abstract

Read online

In the present study, carboxymethyl cellulose nanofibrils (CMCNFs) with different carboxyl content (0.99–2.01 mmol/g) were prepared via controlling the ratio of monochloroacetic acid (MCA) and sodium hydroxide to Eucalyptus bleached pulp (EBP). CMCFs-PEI aerogels were obtained using the crosslinking reaction of polyethyleneimine (PEI) and CMCNFs with the aid of glutaraldehyde (GA). The effects of pH, contact time, temperature, and initial Cu2+ concentration on the Cu2+ removal performance of CMCNFs-PEI aerogels was highlighted. Experimental data showed that the maximum adsorption capacity of CMCNF30-PEI for Cu2+ was 380.03 ± 23 mg/g, and the adsorption results were consistent with Langmuir isotherm (R2 > 0.99). The theoretical maximum adsorption capacity was 616.48 mg/g. After being treated with 0.05 M EDTA solution, the aerogel retained an 85% removal performance after three adsorption–desorption cycles. X-ray photoelectron spectroscopy (XPS) results demonstrated that complexation was the main Cu2+ adsorption mechanism. The excellent Cu2+ adsorption capacity of CMCNFs-PEI aerogels provided another avenue for the utilization of cellulose nanofibrils in the wastewater treatment field.

Keywords