Acta Crystallographica Section E (Sep 2013)

(Z)-N-(2,6-Diisopropylphenyl)-4-nitrobenzimidoyl chloride

  • Gamal A. El-Hiti,
  • Keith Smith,
  • Dyfyr Heulyn Jones,
  • Ali Masmali,
  • Benson M. Kariuki

DOI
https://doi.org/10.1107/S1600536813020862
Journal volume & issue
Vol. 69, no. 9
pp. o1384 – o1384

Abstract

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In the title compound, C19H21ClN2O2, the aromatic rings are approximately perpendicular to each other, subtending a dihedral angle of 87.7 (1)°. In the crystal, the 4-nitrophenyl groups of pairs of neighbouring molecules are parallel and oriented head-to-tail with a ring centroid–centroid distance of 3.9247 (12) Å, leading to a π–π interaction between the pair. The faces of each phenyl ring of the 2,6-diisopropylphenyl group interact with two different groups, viz. a chloro group of an adjacent molecule on one side and the edge of the 4-nitrophenyl ring of a second molecule on the other side.