Film Carbon Veil-Based Electrode Modified with Triton X-100 for Nitrite Determination

Abstract

A film carbon veil-based electrode (FCVE) modified with non-ionic surfactant Triton X-100 (TrX100) has been developed for nitrite determination. A new simple and producible technique of hot lamination (heat sealing) has been used for the FCVE manufacturing. The paper presents the findings of investigating the FCVE and the TrX100/FCVE by using voltammetry, chronoamperometry, and scanning electron microscopy. Modification of the electrode with TrX100 improves the hydrophilic property of its surface, which results in a larger electrode active area and higher sensitivity. Optimal conditions for nitrite determination with the use of the TrX100/FCVE have been identified. The linear range (LR) and the limit of detection (LOD) are 0.1–100 μM and 0.01 μM, respectively. The relative standard deviation (RSD) does not exceed 2.3%. High selectivity of the sensor ensures its successful application for the analysis of real samples (sausage products and natural water). The obtained results accord well with the results of the standard spectrophotometric method.

Keywords

• carbon veil
• hot lamination
• surfactant
• film sensor
• nitrite
• natural water