CS@Cu2O and magnetic Fe3O4@SiO2-pAMBA-CS-Cu2O as heterogeneous catalysts for CuAAC click reaction

Abstract

The recovery of agricultural and food wastes are one of the main areas of current research for optimal biowaste management to reduce greenhouse gas (GHG) emissions that are generated when it is not properly treated. Corn silk (CS) as biowaste from the agricultural sector is a rich source of natural compounds especially polysaccharides. We present here a chemical activation method to convert CS to values added heterogeneous catalyst for the synthesis of triazoles compounds via copper catalyzed azide–alkyne cycloaddition (CuAAC) reaction. For this purpose, cuprous oxide coated CS (CS@Cu2O) and multifunctional Fe3O4@SiO2–para-aminomethyl benzoic acid–CS–Cu2O composite (denoted as Fe3O4@SiO2‐pAMBA-CS‐Cu2O) were fabricated. Different analytical techniques have been used to describe the size, crystal structure, elemental composition and other physical properties of the fabricated catalysts. These heterogeneous catalysts showed excellent catalytic activities for the synthesis of 1,4-disubstituted-1,2,3-triazoles via click reaction in H2O at 70 °C under base and external-reductant-free conditions. The magnetic properties of the catalyst allowed easy separation after reaction by simply applying an external magnet. Other advantages of this work are the recyclability of the catalyst, the absence of reducing agent and base, besides utilisation of bio wastes for the production of heterogeneous catalyst.

Keywords

• Click chemistry
• Bio-waste
• Corn Silk
• Heterogeneous catalysts
• Magnetic nanoparticles
• Triazole