Experimental and kinetic study of sulfur dioxide adsorption reaction generated from jet fuel combustion by sodium carbonate sorbent using the random pore model
Iman Omidi,
Hamed Forootan,
Majid Mazhar,
Hossein Mohammad Karimi Yazdi,
Mohammad Mehdi Barjesteh
Affiliations
Iman Omidi
Chemical Engineering Department, College of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran
Hamed Forootan
Polymer Engineering Department, College of Inorganic Pigments and Glazes, Institute for Color Science and Technology, Tehran, Iran
Background and Objectives: SO2 pollution has become a serious concern. The aim of this study is SO2 removal from JP-4 fuel combustion. Materials and Methods: Experiments were performed by thermogravimetric analysis at different temperatures and various SO2 concentration. Kinetic study of non-catalytic gas-solid reaction was performed using mathematical modeling based on random pore model. Results: The pore size distribution curve was obtained. The structural parameters of the random pore model were measured as r=1.92×10-5, ε0=0.64, S0=1.27×106 and ψ=3.81. Thermogravimetry diagram and conversion-time curves were extracted. Fractional reaction modeling is obtained based on gas reactant. Conclusion: The obtained kinetic parameters can be used to design flue gas desulfurization systems at low temperatures.
