Synthesis of Cobalt Complex Containing <i>Trans</i>-Cinnamate and Its Electrocatalytic Activity for Oxygen Evolution Reaction

Abstract

There are many efforts reported on finding effective catalysts for oxygen evolution reactions (OERs), which are important reactions in the energy field. Coordination polymers, including metal–organic frameworks (MOFs), are attracting attention as electrocatalysts for OERs due to their versatility and modulating properties. A new cobalt complex containing trans-cinnamate and 2-aminopyridmidine ligands was synthesized using a hydrothermal method. The cobalt complex showed a 1D chain structure. The electrocatalytic activity and stability of the cobalt complex with or without an electrochemical supporter, such as reduced graphene oxide (rGO), OERs were investigated and compared with a metal oxide reference material. Due to the π-conjugated trans-cinnamate, which has electron flexibility near the Co centers, the catalyst/rGO composite showed significant catalytic activities, with an overpotential of 386 mV and a Tafel slope of 64 mV/dec.

Keywords

• oxygen evolution reaction
• electrocatalyst
• coordination polymers
• metal–organic  frameworks
• cobalt complex