Preparation and electrochemical properties of Na3V2(PO4)3/C cathode materials from spent electroless nickel plating bath

Abstract

Through a sol-gel method, a honeycomb-like Na _3 V _2 (PO _4 ) _3 /C cathode material for sodium-ion batteries was synthesized from a spent electroless nickel plating bath. The obtained Na _3 V _2 (PO _4 ) _3 /C exhibited excellent electrochemical properties, with the initial discharge capacity of 108.3 mAh·g ^−1 at 0.2 C and the capacity retention of 99.3% after 300 cycles, which was comparable to that of powders prepared from chemical reagents. This study will be helpful for the value-adding utilization of the spent electroless nickel plating bath.

Keywords

• sodium-ion batteries
• Na3V2(PO4)3/C
• sol-gel preparation
• spent electroless nickel plating bath
• value-adding utilization