High-efficiency laminated luminescent solar concentrators based on carbon dots and nanorings

Danzhou Huang; Zhiwen Hua; Xinchu Wang; Jiaheng Yan; Wei Xin; Jinhua Li; Xianbao Wang; Lai Wei; Jianying Wang

Next Materials (Oct 2024)

High-efficiency laminated luminescent solar concentrators based on carbon dots and nanorings

Danzhou Huang,
Zhiwen Hua,
Xinchu Wang,
Jiaheng Yan,
Wei Xin,
Jinhua Li,
Xianbao Wang,
Lai Wei,
Jianying Wang

Affiliations

Danzhou Huang: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China
Zhiwen Hua: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China
Xinchu Wang: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China
Jiaheng Yan: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China
Wei Xin: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China
Jinhua Li: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China; Corresponding authors.
Xianbao Wang: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China
Lai Wei: Wuhan Drug Solubilization and Delivery Technology Research Center, School of Life and Health, Wuhan Vocational College of Software and Engineering, Wuhan 430205, PR China; Corresponding authors.
Jianying Wang: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, PR China; Corresponding author at: Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, PR China.

Journal volume & issue: Vol. 5
p. 100277

Abstract

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Creation of novel fluorescent nanomaterials with high photoluminescence quantum yield (PLQY) will lead to high-efficiency luminescent solar concentrators (LSCs). Herein, two kinds of carbon dots (CDs), e.g., blue and green emissive CDs and one novel carbon nanorings (NRs) with yellow emission are synthesized by the solvothermal method. Diaminobenzenesulfonic acid is used as one main precursor to create blue, green emission carbon dots (B/GCDs) and yellow emission carbon nanorings (YCNRs). Importantly, the PLQYs of B/GCDs and YCNRs are 59.8±3.2 %, 12.2±0.7 % and 63.2±1.5 %, respectively. Moreover, B/GCDs and YCNRs are used as fluorescent nanomaterials to construct laminated LSCs with single-layer and double-layer through one-step photopolymerization technique. For single-layer laminated LSCs, YCNRs-based LSCs have the maximum external optical efficiency (ηopt), up to 3.05 %. Furthermore, for double-layer laminated LSCs, the LSCs based on BCDs and YCNRs achieve the highest ηopt of 4.09 %. Compared to single-layer laminated LSCs, the double-layer laminated LSCs show an increase of 34 % in ηopt. Their internal quantum efficiency (ηint) of 29.88 % and external quantum efficiency (ηext) of 25.18 % are obtained, respectively. The presented values are just for single-wavelength excitation. Thus, the synthesis of novel YCNRs with high PLQYs contributes to the optical performances at a large level. Remarkably, the optimal double-layer laminated LSCs show good transparency.

Published in Next Materials

ISSN: 2949-8228 (Online)
Publisher: Elsevier
Country of publisher: United Kingdom
LCC subjects: Technology
Website: https://www.sciencedirect.com/journal/next-materials

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