Baseflow is the part of streamflow that is mainly replenished by groundwater. The protection of the biological environment and the growth of its water resources greatly depend on the spatial and temporal evolution of baseflow. Therefore, the Baizhiao (BZA) and Shaduan (SD) catchments of the Jiaojiang River Basin (JRB) in the Zhejiang province of China were selected as study areas. The ABCD model and Eckhardt method were used to calculate baseflow and baseflow index (BFI). The temporal and spatial evolution patterns of baseflow were analyzed through statistical analysis and the Mann–Kendall test. The results showed that the ABCD model performs well in simulating overall hydrological processes on the monthly streamflow at BAZ and SD stations with NSE (Nash–Sutcliffe Efficiency) values of 0.82 and 0.83 and Pbias (Percentage Bias) values of 9.2% and 8.61%, respectively. The spatial–temporal distribution of the BFI indicates the higher baseflow contribution in upstream areas compared to downstream areas at both stations. The baseflow and BFI had significant upward trends at the BZA and SD stations in the dry season, while their trends were not uniform during the wet period. These findings are essential guidance for water resource management in the JRB regions.