Nature Communications (Jul 2022)
Photocatalytic dehydrogenative C-C coupling of acetonitrile to succinonitrile
- Xian Zhou,
- Xiaofeng Gao,
- Mingjie Liu,
- Zirui Gao,
- Xuetao Qin,
- Wenhao Xu,
- Shitong Ye,
- Wenhua Zhou,
- Haoan Fan,
- Jing Li,
- Shurui Fan,
- Lei Yang,
- Jie Fu,
- Dequan Xiao,
- Lili Lin,
- Ding Ma,
- Siyu Yao
Affiliations
- Xian Zhou
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Xiaofeng Gao
- Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, Peking University
- Mingjie Liu
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Zirui Gao
- Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, Peking University
- Xuetao Qin
- Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, Peking University
- Wenhao Xu
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Shitong Ye
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Wenhua Zhou
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Haoan Fan
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Jing Li
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Shurui Fan
- Institute of Industrial Catalysis, State Key Laboratory of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology
- Lei Yang
- Zhejiang Henglan Science and Technology Co. Ltd
- Jie Fu
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- Dequan Xiao
- Center for Integrative Materials Discovery, Department of Chemistry and Chemical and Biomedical Engineering, University of New Haven
- Lili Lin
- Institute of Industrial Catalysis, State Key Laboratory of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology
- Ding Ma
- Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, Peking University
- Siyu Yao
- Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University
- DOI
- https://doi.org/10.1038/s41467-022-32137-y
- Journal volume & issue
-
Vol. 13,
no. 1
pp. 1 – 8
Abstract
The coupling of acetonitrile into succinonitrile via a dehydrogenative route is highly attractive in terms of valuable chemical synthesis and green hydrogen energy production. Here, the authors report succinonitrile synthesis with high selectivity and rate via a light driven dehydrogenative coupling reaction of CH3CN over the anatase TiO2 supported Pt catalyst.
