Management of waste containing polybrominated diphenyl ethers: A review

Abstract

Polybrominated diphenyl ethers (PBDEs) are substances used as flame retardants that can be released into the environment through volatilization, leaching, and abrasion throughout the useful life of the articles that contain them, especially at the end of their life cycle because PBDEs do not chemically bind to the initial materials (electrical and electronic equipment, textiles, materials used in transport vehicles, toys, among others). Research has shown that the toxic effects and risks of PBDEs to ecosystems and human health are greater than their benefits owing to their neurotoxicity, toxicity to the endocrine and reproductive systems, and possible carcinogenicity. This review shows the current situation of management of waste containing PBDEs (plastics, sludge, soil, and ash) and the characterization, valorization, treatment, and final disposal of these wastes, to minimize their impacts on ecosystems and human health are analyzed. Wastes with concentrations greater than 1000 mg/kg of PBDE should be considered as hazardous waste. This research identifies the methods available to reduce the risk in their management; at the same time, it provides innovative ideas for the integrated management of PBDE-containing wastes, prioritizing their valorization and disposal.

Keywords

• Persistent organic pollutants
• Pretreatment
• Pyrolysis
• Waste management cycle