4-Benzyl-6-bromo-2-(4-methoxyphenyl)-4H-imidazo[4,5-b]pyridine monohydrate

Abstract

The imidazopyridine fused ring in the title compound, C20H16BrN3O·H2O, is coplanar with the aromatic ring at the 2-position [dihedral angle = 5.2 (1)°]. In the five-membered imidazo portion, the C—N bond whose C atom is also connected to the pyridine N atom has predominantly double-bond character [1.334 (2) Å] whereas the C—N bond whose atom is connected to the pyridine C atom has predominantly single-bond character [1.371 (2) Å]. The water molecule engages in hydrogen bonding with the latter N atom; it is also connected to a symmetry-related water molecule, generating a linear chain structure.