Numerical and Experimental Investigations of CH₄/H₂ Mixtures: Ignition Delay Times, Laminar Burning Velocity and Extinction Limits

Abstract

In this work, the influence of H2 addition on the auto-ignition and combustion properties of CH4 is investigated experimentally and numerically. Experimental ignition delay times (IDT) are compared with simulations and laminar burning velocities (LBVs), and extinction limits/extinction strain rates (ESRs) are compared with data from the literature. A wide variety of literature data are collected and reviewed, and experimental data points are extracted for IDT, LBV and ESR. The results are used for the validation of existing reaction mechanisms. The reaction mechanisms and models used are able to reproduce the influence of H2 addition to CH4 (e.g., shortening IDTs, increasing ESRs and increasing LBVs). IDTs are investigated in a range from 6 to 15 bar and temperatures from 929 to 1165 K with H2 addition from 10 to 100 mol%. We show that LBV and ESR are predicted in a wide range by the numerical simulations. Moreover, the numerical simulations using detailed Aramco Mech 3.0 (581 species) are compared with the derived reduced reaction mechanism UCB Chen (49 species). The results show that the reduced chemistry obtained by considering only the IDT is also valid for LBV and ESR.

Keywords

• methane
• hydrogen
• ignition delay times
• rapid compression machine
• laminar burning velocity
• extinction limit