Molecules (Oct 2024)

Ideal Photothermal Materials Based on Ge Subwavelength Structure

  • Jingjun Wu,
  • Kaixuan Wang,
  • Cong Wei,
  • Jun Ma,
  • Hongbo Xu,
  • Wanguo Zheng,
  • Rihong Zhu

DOI
https://doi.org/10.3390/molecules29215008
Journal volume & issue
Vol. 29, no. 21
p. 5008

Abstract

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Photothermal materials often prioritize solar absorption while neglecting thermal radiation losses, which diminishes thermal radiation conversion efficiency. This study addresses this gap by introducing a germanium (Ge) subwavelength structure (SWS) designed to optimize both solar absorption and infrared emissivity. Using a self-masked reactive ion etching (RIE) technique, we achieved a peak absorption of 98.8% within the 300 nm to 1800 nm range, with an infrared emissivity as low as 0.32. Under solar illumination of 1000 W/m2, the structure’s temperature increased by 50 °C, generating a heating power of 800 W/m2. Additionally, it demonstrated good mechanical and thermal stability at high temperatures and possessed a hydrophobic angle of 132°, ensuring effective self-cleaning. These characteristics make the Ge SWS suitable for application in solar panels, displays, sensors, and other optoelectronic devices.

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