3-(4-Chlorophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazole-1-carbothioamide

Abstract

In the title compound, C16H13ClFN3S, the pyrazole ring adopts an envelope conformation with the methine C atom being the flap atom. The chloro- and fluorobenzene rings are twisted out of the plane of the pyrazole ring [dihedral angles = 15.12 (11) and 80.55 (10)°, respectively]. The amine group is orientated towards a ring N atom, forming an intramolecular N—H...N hydrogen bond. This H atom also forms a hydrogen bond to the F atom, which along with N—H...S hydrogen bonding leads to a supramolecular chain along the c axis. Connections between chains of the type Cl...π lead to a layer in the bc plane.