Exploring the Frontiers of Cathode Catalysts in Lithium–Carbon Dioxide Batteries: A Mini Review

Abstract

To mitigate the greenhouse effect and environmental pollution caused by the consumption of fossil fuels, recent research has focused on developing renewable energy sources and new high-efficiency, environmentally friendly energy storage technologies. Among these, Li–CO2 batteries have shown great potential due to their high energy density, long discharge plateau, and environmental friendliness, offering a promising solution for achieving carbon neutrality while advancing energy storage devices. However, the slow kinetics of the CO2 reduction reaction and the accumulation of Li2CO3 discharge on the cathode surface lead to a significant reduction in space and active sites. This in turn results in high discharge overpotential, low energy efficiency, and low power density. This study elucidates the charge–discharge reaction mechanisms of lithium–carbon dioxide batteries and systematically analyzes their reaction products. It also summarizes the latest research advancements in cathode materials for these batteries. Furthermore, it proposes future directions and efforts for the development of Li–CO2 batteries.

Keywords

• lithium–carbon dioxide battery
• electrode material
• catalyst
• first principles
• electrochemical performance