Heliyon (Apr 2024)
Fabrication and synergistically enhanced photocatalytic activity of ternary kaolinite, TiO2, and Al2O3 (K65T30A5) nanocomposite for visible-light-induced degradation of methylene blue and remazol red dye
Abstract
The ternary photocatalyst ((Al2Si2O5 (OH)4/TiO2/Al2O3) composites (where w/w = 65, 30, and 5 wt%) denoted K65T30A5 were successfully synthesized and examined for their efficiency in removing cationic (Methylene Blue, MB) and anionic (Remazol Red, RR) dye from aqueous medium under visible-light irradiation. A series of nanocomposites with varied wt% of kaolinite, TiO2, and Al2O3 were prepared through sonication followed by calcination at 600 °C. X-ray diffraction (XRD) analysis confirmed the crystallinity of the synthesized materials and established their average crystal size to be 83.87 nm. The morphological structure, composite molecule, and surface properties of the resulting K65T30A5 were characterized using FTIR, FE-SEM, and EDS analyses to confirm the successful fabrication of the nanocomposite. FTIR and EDS elemental mapping analyses confirmed the presence of Al, Si, Ti, and O elements in the nanocomposites. The composites exhibited photocatalytic behaviour across the UV–visible spectra, with values varying from the ultraviolet to the visible region with a sharp increase in reflectance at 510 nm. Near-complete degradation of MB (97.66 %) was achieved within 90 min at pH 9 and a 10 mg/L dye concentration, while RR removal reached 90.66 % within 120 min at pH 3.5 and the same dye concentration under visible light irradiation. The catalyst exhibited robust stability, retaining its efficiency by removing 85.09 % of MB and 80.21 % of RR dye after three reuse cycles. The composite catalyst discussed in this study emerges as a promising material for straightforward fabrication techniques, featuring a high percentage of kaolinite and proving to be a cost-effective solution for large-scale water and wastewater treatment processes.
