Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries

Sajeela Awasthi; Srikanta Moharana; Vaneet Kumar; Nannan Wang; Elham Chmanehpour; Anupam Deep Sharma; Santosh K. Tiwari; Vijay Kumar; Yogendra Kumar Mishra

Nano Materials Science (Oct 2024)

Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries

Sajeela Awasthi,
Srikanta Moharana,
Vaneet Kumar,
Nannan Wang,
Elham Chmanehpour,
Anupam Deep Sharma,
Santosh K. Tiwari,
Vijay Kumar,
Yogendra Kumar Mishra

Affiliations

Sajeela Awasthi: Department of Applied Sciences, CT Institute of Engineering, Management and Technology, CT Group of Institutions, Shahpur, India
Srikanta Moharana: School of Applied Sciences, Centurion University of Technology and Management, Odisha, India
Vaneet Kumar: CTIEMT, Department of Applied Sciences, CT Group of Institutions, Jalandhar, Punjab, India
Nannan Wang: Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environment and Materials, Guangxi University, Nanning, China
Elham Chmanehpour: Smart Materials, NanoSYD, Mads Clausen Institute, University of Southern Denmark, Alsion 2, Sønderborg, 6400, Denmark
Anupam Deep Sharma: Department of Applied Sciences, Chandigarh Group of Colleges, Jhanjeri, Mohali, Punjab, India
Santosh K. Tiwari: Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environment and Materials, Guangxi University, Nanning, China; Centre for New Materials and Surface Engineering, NMAMIT, Nitte (Deemed to be university), Nitte, 574110, Karnataka, India; Corresponding author. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environment and Materials, Guangxi University, Nanning, China.
Vijay Kumar: Department of Physics, National Institute of Technology Srinagar, Jammu and Kashmir, 190006, India; Corresponding author.
Yogendra Kumar Mishra: Smart Materials, NanoSYD, Mads Clausen Institute, University of Southern Denmark, Alsion 2, Sønderborg, 6400, Denmark; Corresponding author.

Journal volume & issue: Vol. 6, no. 5
pp. 504 – 535

Abstract

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Polyanion-based materials are considered one of the most attractive and promising cathode materials for lithium-ion batteries (LIBs) due to their good stability, safety, cost-effectiveness, suitable voltages, and minimal environmental impact. However, these materials suffer from poor rate capability and low-temperature performance owing to limited electronic and ionic conductivity, which restricts their practical applicability. Recent developments, such as coating material particles with carbon or a conductive polymer, crystal deformation through the doping of foreign metal ions, and the production of nanostructured materials, have significantly enhanced the electrochemical performances of these materials. The successful applications of polyanion-based materials, especially in lithium-ion batteries, have been extensively reported. This comprehensive review discusses the current progress in crystal deformation in polyanion-based cathode materials, including phosphates, fluorophosphates, pyrophosphates, borates, silicates, sulfates, fluorosilicates, and oxalates. Therefore, this review provides detailed discussions on their synthesis strategies, electrochemical performance, and the doping of various ions.

Published in Nano Materials Science

ISSN: 2589-9651 (Online)
Publisher: KeAi Communications Co., Ltd.
Country of publisher: China
LCC subjects: Technology: Engineering (General). Civil engineering (General)
Website: https://www.keaipublishing.com/en/journals/nano-materials-science/

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