Acta Crystallographica Section E (Nov 2009)

Bis(2,3,5-triphenyltetrazolium) tetrathiocyanatocobaltate(II)

  • Kouichi Nakashima,
  • Naoyuki Kawame,
  • Yoshiko Kawamura,
  • Osamu Tamada,
  • Jun Yamauchi

DOI
https://doi.org/10.1107/S1600536809041464
Journal volume & issue
Vol. 65, no. 11
pp. m1406 – m1407

Abstract

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The title compound, (C19H15N4)2[Co(NCS)4], has two crystallographycally different molecules of bis(2,3,5-triphenyltetrazolium) tetrathiocyanatecobaltate in the asymmetric unit. There are only minor geometric differences between them. Each cobalt(II) ion is coordinated by the N atoms of four NCS anions, showing the magnitude of the magnetic moment expected from the NCS− crystal field strength.