Chromatic dispersion and thermal coefficients of hygroscopic liquids: 5 glycols and glycerol

Abstract

Abstract Chromatic dispersion and thermal coefficients of 6 hygroscopic liquids: ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol (propane-1, 2-diol), and glycerol were measured in the range from 390 to 1070 nm for temperatures from 1 to 45 °C. A modified Abbe refractometer was utilised. Special care was taken to avoid contaminating the liquids under the test with water and solid particles. The measurement uncertainties were analysed. It was noticed that (in the given range and within the available measurement accuracy) the dependence of the refractive indices on the wavelength and temperature could be considered independently. Thus, thermal coefficients were found for each wavelength used, and their weak dependence on the wavelength was recognised. Then the Sellmeier equation was fitted to the experimental results for each temperature.