Fabrication of Structured Boron-Doped Diamond Films for Electrochemical Applications
Tibor Ižák,
Ondrej Szabó,
Pavla Štenclová,
Štěpán Potocký,
Vlastimil Vyskočil,
Alexander Kromka
Affiliations
Tibor Ižák
Institute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200 Prague 6, Czech Republic
Ondrej Szabó
Institute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200 Prague 6, Czech Republic
Pavla Štenclová
Institute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200 Prague 6, Czech Republic
Štěpán Potocký
Institute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200 Prague 6, Czech Republic
Vlastimil Vyskočil
UNESCO Laboratory of Environmental Electrochemistry, Department of Analytical Chemistry, Faculty of Science, Charles University, Albertov 6, 12843 Prague 2, Czech Republic
Alexander Kromka
Institute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 16200 Prague 6, Czech Republic
In the present study, we introduce various technological approaches for fabrication of structured boron-doped diamond (BDD) electrodes, i.e., nanocones and nanorods which are used as working electrodes for electrochemical measurements. Structured BDD were realized either by reactive ion etching employing gold nanoclusters as the mask or by thermo-catalytically induced modification of the diamond surface. All samples were characterized in terms of surface morphology (scanning electron microscopy images), chemical composition (Raman spectroscopy) and electrochemical properties (anodic stripping voltammetry).