Nature Communications (Feb 2019)

Catalytic inverse vulcanization

  • Xiaofeng Wu,
  • Jessica A. Smith,
  • Samuel Petcher,
  • Bowen Zhang,
  • Douglas J. Parker,
  • John M. Griffin,
  • Tom Hasell

DOI
https://doi.org/10.1038/s41467-019-08430-8
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 9

Abstract

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Inverse vulcanization allows stable polymers to be made from elemental sulfur, but development is restricted by cross-linkers and the elevated temperatures required. Here the authors report a catalytic method for a wide range of cross-linkers and found a reduced reaction temperature and reaction time is required.