Two-dimensional titanium carbide MXene produced by ternary cations intercalation via structural control with angstrom-level precision
Zehai Xu,
Yufan Zhang,
Minmin Liu,
Qin Meng,
Chong Shen,
Lushen Xu,
Guoliang Zhang,
Congjie Gao
Affiliations
Zehai Xu
Center for Membrane and Water Science & Technology, Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China
Yufan Zhang
College of Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA
Minmin Liu
Center for Membrane and Water Science & Technology, Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China
Qin Meng
College of Chemical and Biological Engineering, State Key Laboratory of Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China
Chong Shen
Center for Membrane and Water Science & Technology, Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China; College of Chemical and Biological Engineering, State Key Laboratory of Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China
Lushen Xu
Center for Membrane and Water Science & Technology, Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China
Guoliang Zhang
Center for Membrane and Water Science & Technology, Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China; Corresponding author
Congjie Gao
Center for Membrane and Water Science & Technology, Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China
Summary: Highly effective decontamination of lead is a primary challenge for ecosystem protection and public health. Herein, we report a methodology of ternary cations intercalation to synthesize Ti3C2Tx MXene by structural control with angstrom-level precision through mixed fluorinated salts wet etching-alkalization approach for high-efficient lead adsorption. The successive introduction of lithium, potassium, and sodium ions continuously weakens interaction forces between Ti3C2Tx layers, resulting in achieving fine tailored interlayer distance from 9.8 to 15.9 Å. A high density of complexing groups are formed after ternary cations intercalation, which greatly improve the hydrophilicity of Ti3C2Tx to enhance the accessibility and shorten the mass transfer and provide abundant adsorption sites to exhibit strong complexing effects with lead ions. The prepared ternary cations-intercalated Ti3C2Tx nanosheets exhibited a high adsorption capacity (267.2 mg/g) toward lead ions and sharply cut down lead concentration from 10 to 0.009 mg/L, far below the drinking water standards (0.015 mg/L).
