Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed (de)hydrogenation

Zhihui Shao; Yang Li; Chenguang Liu; Wenying Ai; Shu-Ping Luo; Qiang Liu

doi:10.1038/s41467-020-14380-3

Nature Communications (Jan 2020)

Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed (de)hydrogenation

Zhihui Shao,
Yang Li,
Chenguang Liu,
Wenying Ai,
Shu-Ping Luo,
Qiang Liu

Affiliations

Zhihui Shao: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University
Yang Li: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University
Chenguang Liu: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University
Wenying Ai: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University
Shu-Ping Luo: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology
Qiang Liu: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University

DOI: https://doi.org/10.1038/s41467-020-14380-3
Journal volume & issue: Vol. 11, no. 1
pp. 1 – 7

Abstract

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The development of cost-effective, sustainable, and efficient catalysts for liquid organic hydrogen carrier systems is a significant goal. Herein, authors present a system based on manganese catalysis with a theoretical H2 capacity of 5.3 wt% and high selectivity for the dehydrogenation reaction.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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