Acta Crystallographica Section E (May 2011)

(8S,9S,10R)-4-(4-Chlorobenzyloxy)-7,8-didehydro-3,7-dimethoxy-17-methylmorphinan-6-one monohydrate

  • Xing-Liang Zheng,
  • Shu-Jun Chen,
  • Ning-Fei Jiang,
  • Sue-Hui Zhan

DOI
https://doi.org/10.1107/S1600536811013973
Journal volume & issue
Vol. 67, no. 5
pp. o1190 – o1190

Abstract

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In the title compound, C26H28ClNO4·H2O, the dihedral angle betwene the two aromatic rings is 69.73 (6)°. The N-containing ring exhibits a chair conformation, while the other non-aromatic rings are in approximate envelope conformations. In the crystal, the water molecule forms O—H...O and O—H...N hydrogen bonds and a C—H...O link also occurs.