Acta Crystallographica Section E (Feb 2008)

Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ3O,N,N′]copper(II) tetrahydrate

  • Ru-Wen Qing,
  • Shang-Shang Zhang,
  • Cui-Wu Lin,
  • Fei-Long Hu,
  • Xian-Hong Yin,
  • Kai Zhao

DOI
https://doi.org/10.1107/S1600536807068110
Journal volume & issue
Vol. 64, no. 2
pp. m284 – m285

Abstract

Read online

In the title complex, [Cu(C11H9ClN3O2)2]·4H2O, the CuII atom is in a distorted octahedral coordination environment, coordinated by four N atoms and two O atoms from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The molecules are linked via intermolecular O—H...O hydrogen bonds involving water molecules to form extended chains along [010], and there are short Cl...Cl contacts [3.153 (4) Å].