Molecules (Nov 2022)

Removal of Malachite Green Dye from Aqueous Solution by Catalytic Wet Oxidation Technique Using Ni/Kaolin as Catalyst

  • Abdelhak Moumen,
  • Youghourta Belhocine,
  • Najoua Sbei,
  • Seyfeddine Rahali,
  • Fatima Adam Mohamed Ali,
  • Fedia Mechati,
  • Fouad Hamdaoui,
  • Mahamadou Seydou

DOI
https://doi.org/10.3390/molecules27217528
Journal volume & issue
Vol. 27, no. 21
p. 7528

Abstract

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In this study, natural Algerian kaolin was used as a support and impregnated with nickel at different loading amounts (2 wt.%, 5 wt.%, and 7 wt.%) in order to prepare a supported catalyst. The wet impregnation technique was used in this preparation; nickel oxide (NiO) was the active phase precursor of the catalyst, and the catalysts were designated as follows: 2%, 5%, and 7% Ni/kaolin. These catalysts were put to the test in catalytic wet peroxide oxidation (CWPO) for degrading the organic contaminant malachite green dye (MG). Analytical techniques such as FTIR spectroscopy, X-ray diffraction, BET, and X-fluorescence were used to examine the structure, morphology, and chemical composition of the support and the produced catalysts. Several parameters, including temperature, catalytic dose, metal loading, hydrogen peroxide volume, and kinetic model were systematically investigated. The combination of improved parameters resulted in a significant increase in the catalytic activity, achieving a high removal rate of MG dye of 98.87%.

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