Acta Crystallographica Section E (Nov 2008)

[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ3P,C1,P′](nitrato-κO)nickel(II)

  • Brian J. Boro,
  • Diane A. Dickie,
  • Eileen N. Duesler,
  • Karen I. Goldberg,
  • Richard A. Kemp

DOI
https://doi.org/10.1107/S1600536808032376
Journal volume & issue
Vol. 64, no. 11
pp. m1402 – m1402

Abstract

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The NiII atom in the title compound, [Ni(C24H43P2)(NO3)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positions of 50% occupancy for the other atoms of the nitrate group.