Fluorescence Properties of ZnOQDs-GO-g-C₃N₄ Nanocomposites

Abstract

In this paper, the fluorescence properties of ZnOQD-GO-g-C3N4 composite materials (ZCGQDs) were studied. Firstly, the addition of a silane coupling agent (APTES) in the synthesis process was explored, and it was found that the addition of 0.04 g·mL−1 APTES had the largest relative fluorescence intensity and the highest quenching efficiency. The selectivity of ZCGQDs for metal ions was also investigated, and it was found that ZCGQDs showed good selectivity for Cu2+. ZCGQDs were optimally mixed with Cu2+ for 15 min. ZCGQDs also had good anti-interference capability toward Cu2+. There was a linear relationship between the concentration of Cu2+ and the fluorescence intensity of ZCGQDs in the range of 1~100 µM. The regression equation was found to be F0/F = 0.9687 + 0.12343C. The detection limit of Cu2+ was about 1.74 μM. The quenching mechanism was also analyzed.

Keywords

• nanocomposites
• fluorescence probe
• metal ion
• fluorescence properties