Dichloridobis(pyridine-2-selenolato-κ2N,Se)tin(IV)

Acta Crystallographica Section E. 2013;69(7):m364-m365 DOI 10.1107/S1600536813014657

 

Journal Homepage

Journal Title: Acta Crystallographica Section E

ISSN: 1600-5368 (Print)

Publisher: International Union of Crystallography

LCC Subject Category: Science: Chemistry

Country of publisher: United Kingdom

Language of fulltext: English

Full-text formats available: PDF, HTML

 

AUTHORS

Gunay Z. Mammadova
Sheyda R. Ismaylova
Zhanna V. Matsulevich
Vladimir K. Osmanov
Alexander V. Borisov
Victor N. Khrustalev

EDITORIAL INFORMATION

Blind peer review

Editorial Board

Instructions for authors

Time From Submission to Publication: 3 weeks

 

Abstract | Full Text

The title compound, [SnCl2(C5H4NSe)2], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the SnIV atom is a distorted octahedron, with two bidentate 2-pyridineselenolate ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π interactions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak intermolecular C—H...Cl hydrogen bonds link the molecules into chains along the c axis.