Direct-Continuous Preparation of Nanostructured Titania-Silica Using Surfactant-Free Non-Scaffold Rice Starch Template

Abstract

The conventional synthesis route of nanostructured titania-silica (Ti-SiNS) based on sol-gel requires the use of a surfactant-type template that suffers from hazardous risks, environmental concerns, and a tedious stepwise process. Alternatively, biomaterials have been introduced as an indirect template, but still required for pre-suspended scaffold structures, which hinder their practical application. Herein, we report an easy and industrially viable direct-continuous strategy for the preparation of Ti-SiNS from nanostructured-silica (SiNS) using a hydrolyzed rice starch template. This strategy fits into the conventional industrial process flow, as it allows starch to be used directly in time-effective and less complicated steps, with the potential to upscale. The formation of Ti-SiNS is mainly attributed to Ti attachment in the SiNS frameworks after the polycondensation of the sol-gel composition under acidic-media. The SiNS had pseudo-spherical morphology (nanoparticles with the size of 13 to 22 nm), short order crystal structure (amorphous) and high surface area (538.74 m2·g−1). The functionalized SiNS into Ti-SiNS delivered considerable catalytic activity for epoxidation of 1-naphtol into 1,4-naphthoquinone. The described direct-continuous preparation shows great promise for a cheap, green, and efficient synthesis of Ti-SiNS for advanced applications.

Keywords

• nanostructured silica
• surfactant-free
• non-scaffold template
• direct-continuous preparation
• sol-gel synthesis