Zhejiang Daxue xuebao. Lixue ban (May 2022)

Determination of methoxypolybrominated diphenyl ethers in the coastal marine environment using solid-phase extraction and gas chromatography coupled with negative chemical ionization mass spectrometry(固相萃取净化-气相色谱-负化学源质谱法测定近岸海洋环境中的甲氧基多溴联苯醚)

  • GAOWen(郜文),
  • SUNXiumei(孙秀梅),
  • JINYanjian(金衍健),
  • HAOQing(郝青),
  • FUYu(傅宇),
  • YEMaosheng(叶茂盛),
  • YANGChenghu(杨承虎),
  • GUOYuanming(郭远明)

DOI
https://doi.org/10.3785/j.issn.1008-9497.2022.03.012
Journal volume & issue
Vol. 49, no. 3
pp. 344 – 353

Abstract

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甲氧基多溴联苯醚（methoxypolybrominated diphenyl ethers，MeO-PBDEs）广泛存在于生物体和海洋环境。以象山海域的生物体和沉积物为样本，采用固相萃取净化-气相色谱-负化学源质谱法，检测了6种MeO-PBDEs，结果显示，当目标分析物浓度为0.1~20.0 μg∙L−1时，线性关系良好（R2> 0.999），检出限为0.13~0.22 μg∙kg−1，定量限为0.42~0.72 μg∙kg−1，实际样品的平均回收率为71.2%~116.2%。MeO-PBDEs的分布状况调查结果显示，藻类样品中仅检出6-MeO-BDE-47，且浓度较低，其他生物体中检出3种MeO-PBDEs，检出率为31.3%，浓度为0.21~2.72 μg∙kg−1。沉积物中无MeO-PBDEs被检出。

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