The direct acrylation of soybean oil was investigated by the activation of soybean oil’s (SO’s) internal fatty unsaturation with acidic catalysts. The effect of the catalyst and the reactant ratio with respect to the unsaturation and reaction time on the direct acrylation process were explored. ASO (acrylated soybean oil) with acrylation degrees (the number of acrylate molecules introduced in a triglyceride molecule) between 1.6 and 2.55 were obtained. The effect of the ASO acrylation degree on copolymerization processes was investigated. The resulting monomers were successfully copolymerized with meth(acrylate) monomers by the miniemulsion polymerization process, favoring the droplet nucleation mechanism and showing conversions higher than 97%. The acrylic–ASO copolymers presented lower Tg and higher hydrophobicity and oleophobicity than the acrylic copolymer.
