A sound velocity method for determining isobaric specific heat capacity

Abstract

Abstract Isobaric specific heat capacity (Cp) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine Cp by measuring the sound velocity (υ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated Cp at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value.

Keywords

• heat capacity
• sound velocity
• thermoelectric