Preparation of polyethylene glycol brush grafted from the surface of nitrile butadiene rubber with excellent tribological performance under aqueous lubrication

Abstract

The water-lubricated bearing will be in a state of poor lubrication when marine stern shafts operate under low speed and heavy load conditions, which could cause severe wear and vibration, endangering the stealth performance of underwater vehicles. In this study, the grafting of polyethylene glycol brush was carried out on the surface of nitrile butadiene rubber (PEG-g-sNBR) by “grafting from” method. Fourier-transform-infrared-spectroscopy, nuclear-magnetic-resonance, and scanning-electron- microscope results demonstrated that the PEG-g-sNBR brush was successfully synthesized, and the reactive site was found. Using a tribological test machine with a high-precision vibration acceleration sensor, the tribological behaviors of PEG-g-sNBR were studied under aqueous lubrication. The results showed that the coefficient of friction of PEG-g-sNBR was reduced by 73.4% at 100 rpm compared to pure NBR, its microscopic wear and vibrational energy were also lower than pure NBR. Moreover, the lubrication states were revealed by friction, wear, together with the complexity of friction-induced vibration signal time series, and a lubricating film was formed on the friction surface of PEG-g-sNBR at lower rotational speed. In addition, the PEG-g-sNBR could work stably for 12 h at 300 rpm, and still maintain good tribological performance.

Keywords

• Polymer brushes
• Aqueous lubrication
• Coefficient of friction
• Friction-induced vibration