Crystals (Mar 2024)

Study of the Influence of Doping Efficiency of CeO<sub>2</sub> Ceramics with a Stabilizing Additive Y<sub>2</sub>O<sub>3</sub> on Changes in the Strength and Thermophysical Parameters of Ceramics under High-Temperature Irradiation with Heavy Ions

  • Artem L. Kozlovskiy,
  • Sholpan G. Giniyatova,
  • Dmitriy I. Shlimas,
  • Daryn B. Borgekov,
  • Ruslan M. Rspayev,
  • Maxim V. Zdorovets

DOI
https://doi.org/10.3390/cryst14040320
Journal volume & issue
Vol. 14, no. 4
p. 320

Abstract

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The article outlines findings from a comparative analysis of the effectiveness of doping CeO2 ceramics with a stabilizing additive Y2O3 on alterations in the strength and thermophysical parameters of ceramics under high-temperature irradiation with heavy ions comparable in energy to fission fragments of nuclear fuel, which allows, during high-temperature irradiation, to simulate radiation damage that is as similar as possible to the fission processes of nuclear fuel. During the studies, it was found that the addition of a stabilizing additive Y2O3 to the composition of CeO2 ceramics in the case of high-temperature irradiation causes an increase in stability to swelling and softening because of a decrease in the thermal expansion of the crystal lattice by 3–8 times in comparison with unstabilized CeO2 ceramics. It has been determined that the addition of a stabilizing additive Y2O3 leads not only to a rise in the resistance of the crystal structure to deformation distortions and swelling, but also to a decrease in the effect of thermal expansion of the crystal structure, which has an adverse effect on the structural ordering of CeO2 ceramics exposed to irradiation at high temperatures.

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