New Oxidized Zoanthamines from a Canary Islands Zoanthus sp.
Francisco Cen-Pacheco,
Manuel Norte Martín,
José Javier Fernández,
Antonio Hernández Daranas
Affiliations
Francisco Cen-Pacheco
Institute of Bio-Organic Chemistry "Antonio González", Center for Biomedical Research of the Canary Islands, University of La Laguna, 38206 Tenerife, Spain
Manuel Norte Martín
Institute of Bio-Organic Chemistry "Antonio González", Center for Biomedical Research of the Canary Islands, University of La Laguna, 38206 Tenerife, Spain
José Javier Fernández
Institute of Bio-Organic Chemistry "Antonio González", Center for Biomedical Research of the Canary Islands, University of La Laguna, 38206 Tenerife, Spain
Antonio Hernández Daranas
Institute of Bio-Organic Chemistry "Antonio González", Center for Biomedical Research of the Canary Islands, University of La Laguna, 38206 Tenerife, Spain
Three new norzoanthamine-type alkaloids, named 2-hydroxy-11-ketonorzoan thamide B (1), norzoanthamide B (2) and 15-hydroxynorzoanthamine (3), were isolated from Zoanthus sp. specimens collected at the Canary Islands. Their structures were determined by interpretation of NMR and HR-ESIMS data. Relative configurations of their chiral centers were proposed on the basis of ROESY spectra and by comparison of their spectroscopic data with those of the well-known compound, norzoanthamine.
