IUCrData (Nov 2016)

(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)

  • Dame Seye,
  • Cheikh Abdoul Khadir Diop,
  • Libasse Diop,
  • David Renald

DOI
https://doi.org/10.1107/S241431461601840X
Journal volume & issue
Vol. 1, no. 11
p. x161840

Abstract

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The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the three ipso C atoms occupy the equatorial positions. An intramolecular O—H...O hydrogen bond is present in the anion between the hydroxy group and the carbonyl atom O of the carboxylate group.

Keywords