Phosphorus recovery from a pilot-scale grate furnace: influencing factors beyond wet chemical leaching conditions

Abstract

Phosphorus is a non-renewable resource going to be exhausted in the future. Sewage sludge ash is a promising secondary raw material due to its high phosphorus content. In this work, the distribution of 19 elements in bottom and cyclone ashes from pilot-scale grate furnace have been monitored to determine the suitability for the phosphorus acid extraction. Moreover, the influence of some parameters beyond wet chemical leaching conditions were investigated. Experimental results showed that bottom ash presented lower contamination in comparison to cyclone ash and low co-dissolution of heavy metals (especially Cr, Pb and Ni), while high phosphorus extraction efficiencies (76–86%) were achieved. High Al content in the bottom ash (9.4%) negatively affected the phosphorus extraction efficiency as well as loss on ignition, while the particle size reduction was necessary for ensuring a suitable contact surface. The typology of precipitating agents did not strongly affect the phosphorus precipitation, while pH was the key parameter. At pH 3.5–5, phosphorus precipitation efficiencies higher than 90% were achieved, with a mean phosphorus content in the recovered material equal to 16–17%, comparable to commercial fertilizers. Instead, the co-precipitation of Fe and Al had a detrimental effect on the recovered material, indicating the need for additional treatments. HIGHLIGHTS Bottom ashes from pilot-scale grate furnace were suitable for phosphorus extraction.; Influence of parameters beyond chemical extraction conditions were investigated.; Al content and particle size significantly influenced phosphorus extraction efficiency.; pH was the most relevant precipitation parameter unlike the type of precipitating agent.; pH between 3.5 and 5 led to high phosphorus content in the recovered product.;

Keywords

• grate furnace
• heavy metals contamination
• phosphorus recovery
• resource recovery
• sewage sludge ash
• wet chemical extraction and precipitation