REM: International Engineering Journal (Dec 2023)

First occurrence of kitagohaite, Pt7Cu. from the Quadrilátero Ferrífero, Brazil

  • Cristiano Sampaio,
  • Herminio Arias Nalini Jr.,
  • Cristiane Paula de Castro Gonçalves,
  • Geraldo Magela Santos,
  • Ana Ramalho Alkmim

DOI
https://doi.org/10.1590/0370-44672023770030
Journal volume & issue
Vol. 77, no. 1
pp. 83 – 88

Abstract

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Abstract A kitagohaite grain, measuring approximately 1.0 mm, was retrieved from an alluvial gold gravity concentrate from the southeastern Quadrilátero Ferrífero (QFe), Mariana, Brazil. The grain exhibits a cubic structure, whitish-steel-gray, and has a metallic luster. It is composed of Wt. 94.42% Pt and 5.56% Cu (n=9), yielding the empirical formula Pt6.78Cu1.22. This groundbreaking discovery marks the first documented occurrence of kitagohaite in South America. This hydrothermal deposition of kitagohaite indicates that its mineralization is constrained to temperatures <500º C, as inferred by the stability of synthetic Pt7Cu.

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