Heliyon (Jun 2024)
[Nd(NTA)2·H2O]3− complex with high-efficiency emission in NIR region
Abstract
The distinctive photophysical characteristics possessed by lanthanides, including europium, neodymium, and ytterbium, render them adaptable molecular tools for studying biological systems. Specifically, their enduring photoluminescence, precise emission spectra, and significant Stokes shifts allow for experiments not achievable with organic fluorophores or fluorescent proteins. Moreover, the capacity of these metal ions for luminescence resonance energy transfer and photon upconversion extends the potential applications of lanthanide probes even further. In this research, a new [Nd(NTA)2·H2O]3− complex was synthesized and its optical properties were assessed using practical characterization techniques such as UV–Vis absorption, photoluminescence, and FTIR. It was discovered that when the sample was excited by a 357 nm wavelength, it emitted a strong line at 1076 nm with a full-width at half maximum (FWHM) of 10 nm, a phenomenon not previously documented. The Judd-Ofelt theory and its intensity parameters were utilized in a theoretical approach to determine the fluorescence branching ratio and the radiative lifetime of the [Nd(NTA)2·H2O]3− complex. The absorption and luminescence spectra were then analyzed accordingly. Experimental findings validated the potential applications of the prepared sample in bioimaging.
