Facile preparation of alkalized MXene with a larger interlayer for efficient removal of methylene blue

Ying Shi; Xiuying Fang; Yao Zhang; Mingrong Lu; Junxiu Ye; Min Yang; Hongbin Wang; Jiaxiong Li; Guizhen Li

Desalination and Water Treatment (Jan 2025)

Facile preparation of alkalized MXene with a larger interlayer for efficient removal of methylene blue

Ying Shi,
Xiuying Fang,
Yao Zhang,
Mingrong Lu,
Junxiu Ye,
Min Yang,
Hongbin Wang,
Jiaxiong Li,
Guizhen Li

Affiliations

Ying Shi: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Xiuying Fang: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Yao Zhang: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Mingrong Lu: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Junxiu Ye: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Min Yang: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Hongbin Wang: School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Jiaxiong Li: Corresponding authors.; School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China
Guizhen Li: Corresponding authors.; School of Chemistry and Environment, Yunnan Minzu University, Key Laboratory of Resource Clean Conversion in Ethnic Regions, Education Department of Yunnan, Key Laboratory of Environmental Functional Materials of Yunnan Province Education Department, Kunming 650500, PR China

Journal volume & issue: Vol. 321
p. 100992

Abstract

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Ti3C2-MXene is one of the most studied MXenes which are new members of the two-dimensional (2D) material family. It can be fabricated and processed in a variety of scalable and cost-effective way. A novel adsorbent Ti3C2-NaOH was prepared by using NaOH as an intercalating agent to remove dyes in wastewater. The as-prepared Ti3C2-NaOH were analyzed by SEM, XRD, FTIR, Zeta, and BET techniques. The results demonstrate that the material exhibits significant interlayer spacing, with an expansion rate of ,39.94 %, a diverse array of functional groups (-OH, -F), and a considerable specific surface area, featuring pore sizes as large as 13.1969 nm. Furthermore, the effects of adsorbent dosage, initial concentration of MB, time, pH, and temperature on the removal of methylene blue (MB) by Ti3C2-NaOH were investigated. The adsorption capacity of Ti3C2-NaOH could reach 271 mg/g when the adsorption conditions were 20 mg of Ti3C2-NaOH, 293 K, 6 h, and pH 2–6. The adsorption process was well fitted by the Langmuir isotherm model and pseudo-second-order kinetic model. The thermodynamic experiment indicates that Ti3C2-NaOH adsorbing methylene blue is a spontaneous and exothermic process. The mechanisms for MB adsorption onto the Ti3C2-NaOH surface were mainly electrostatic attraction and hydrogen bonding. This work expands the application potential of Ti3C2-NaOH.

Published in Desalination and Water Treatment

ISSN: 1944-3994 (Print); 1944-3986 (Online)
Publisher: Elsevier
Country of publisher: United States
LCC subjects: Technology: Environmental technology. Sanitary engineering; Science: Biology (General): Ecology
Website: https://www.sciencedirect.com/journal/desalination-and-water-treatment

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