Dimetallic praseodymium-cobalt carbon nanotubes as highly efficient electrocatalyst for oxygen reduction reaction
Huazhong Liang,
Yu Dong,
Qin Ding,
Xiaoyu Li,
Miao Yu,
Peihe Li,
Limei Duan,
Yin Wang
Affiliations
Huazhong Liang
Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Yu Dong
Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Qin Ding
Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Xiaoyu Li
Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Miao Yu
Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Peihe Li
Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Limei Duan
Corresponding authors.; Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
Yin Wang
Corresponding authors.; Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Materials Science, Nano Innovation Institute, Inner Mongolia Minzu University, Tongliao 028000, PR China
In this study, six bimetallic rare earth (RE = La, Ce, Pr, Nd, Sm, Eu) cobalt nitrogen doped carbon nanotubes (RECo-NCNTs) were synthesized with g-C3N4 derivative method. These RECo-NCNTs were characterized by SEM, BET, XPS, XRD and Raman. In addition, their catalytic performances for oxygen reduction reaction (ORR) had also been tested. The introduction of rare earths did not destroy the structure of nanotubes but apparently change their ORR performances. The PrCo-NCNTs showed the significant improvement in catalytic ability for ORR (onset potential of 0.95 V and half-wave potential of 0.79 V), which is very close to that of commercial 20 % Pt/C. Moreover, PrCo-NCNTs exhibits an excellent catalytic stability (no activity decay after 10000st cycles) and an outstanding methanol toxic tolerance. Assembled in metal–air batteries (Zn-air, Al-air and Mg-air), the PrCo-NCNTs electrode also presents high power densities and discharge voltages.
