The Construction of Phosphorus-Doped g-C<sub>3</sub>N<sub>4</sub>/Rh-Doped SrTiO<sub>3</sub> with Type-II Band Alignment for Efficient Photocatalytic Hydrogen Evolution
Bin Wang,
Peng Li,
Hanjing Hao,
Huijie He,
Hairui Cai,
Fanfan Shang,
Bei An,
Xiaoqian Li,
Shengchun Yang
Affiliations
Bin Wang
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Peng Li
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Hanjing Hao
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Huijie He
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Hairui Cai
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Fanfan Shang
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Bei An
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Xiaoqian Li
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
Shengchun Yang
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China
It is of great importance to promote charge separation in photocatalysts for enhanced photocatalytic activity under visible light irradiation. In this work, a type-II heterostructured photocatalyst was constructed by compositing phosphorus-doped g-C3N4 (P-CN) and Rh-doped SrTiO3 (Rh-STO) via a thermal calcination treatment. A series of characterizations were conducted to investigate the structure of heterostructured P-CN/Rh-STO. It was found that Rh-STO interacted with in situ generated P atoms from the decomposition of P-CN during the calcination process, thus leading to the formation of heterojunction of P-CN/Rh-STO. Compared with the single component, i.e., P-CN or Rh-STO, the obtained P-CN/Rh-STO showed superior photocatalytic activity to that of both P-CN and Rh-STO due to the effective charge separation across the heterojunction between P-CN and Rh-STO.
