Influence of thermomechanical treatment on the shape memory effect and pseudoelasticity behavior of conventional and additive manufactured Fe–Mn–Si–Cr–Ni-(V,C) shape memory alloys

Abstract

This study evaluated the influence of heat treatment and thermomechanical training on the microstructural evolution and mechanical characteristics of conventional and additive-manufactured FeMnSi-based shape memory alloys. The conventional samples were produced by casting and rolling. The additive-manufactured samples were manufactured using the laser powder bed fusion (L-PBF) technique. Both specimens were subjected to the same heat treatment and thermomechanical training. The heat treatment involved solution annealing at 1050 °C for 2 h and aging at 750 °C for 6 h, and the thermomechanical training concluded with a 4% elongation at ambient temperature followed by annealing at 250 °C for 15 min. This training cycle was repeated four times for each sample after heat treatment. The heat treatment improved the pseudoelasticity and shape memory effect of the samples. Although training further enhanced the pseudoelasticity, it also reduced the shape memory effect. Thermomechanical training led to the formation of a large number of stacking faults, which facilitated the inverse phase transformation of martensite (ε) to austenite (γ) during unloading, resulting in improved pseudoelasticity. The heat-treated additive-manufactured samples showed the highest total recovery strain owing to the pseudoelasticity and shape memory effect. This characteristic could be due to the smaller grain size and higher volume fraction of precipitates. The precipitates and grain refinement improved the conditions for partial dislocation motion by increasing the back stresses on the martensite tip.

Keywords

• Fe-based shape memory alloy
• Pseudoelasticity
• Training
• Shape memory effect
• 4D printing
• Metal AM