Journal of Spectroscopy (Jan 2018)
The Preparation and Characterization of Tourmaline-Containing Functional Copolymer p (VST/MMA/BA)
Abstract
Tourmaline was modified with vinyl triethoxysilane containing double bond to prepare the polymerizable organic vinylsiliconoxyl tourmaline (VST) and then copolymerized with methyl methacrylate (MMA) and butyl acrylate (BA) to produce the tourmaline-containing functional copolymer p (VST/MMA/BA). The structures and morphologies of VST and p (VST/MMA/BA) copolymer were characterized by IR, SEM, and EDX. The experimental results indicated that tourmaline was introduced into the copolymer via surface modification and the tourmaline-containing functional copolymer was obtained by a copolymerization process with MMA and BA. The prepared p (VST/MMA/BA) copolymer displayed excellent storage stabilities, high far-infrared radiation and negative ion releasing performances, and good mechanical properties.