Heterometallic Chain Compounds of Tetrakis(µ-carboxylato)diruthenium and Tetracyanidoaurate

Abstract

Heterometallic complexes of tetrakis(µ-carboxylato)diruthenium(II,III) with tetracyanidoaurate(III) [Ru2(RCOO)4Au(CN)4]n (R = CH3 (1), C2H5 (2), i-C3H7 (3), and t-C4H9 (4)) were synthesized and characterized by C,H,N-elemental analysis and infrared spectroscopy and diffuse reflectance spectroscopy. The molecular structures were determined by a single-crystal X-ray diffraction method. A polymeric arrangement with the Ru2(RCOO)4+ units alternately linked by Au(CN)4− units is formed in these complexes. The trans-bridging mode of the Au(CN)4− unit for connecting the two Ru2(RCOO)4+ units was observed for 1 and 4, while the cis-bridging mode of the Au(CN)4− unit was observed for 2 and 3. Magnetic susceptibility data with variable temperature were modeled with a zero-field splitting model (D = 75 cm−1) and the presence of weak antiferromagnetic coupling between the RuIIRuIII units (zJ = −0.15~−0.10 cm−1) was estimated. N2-adsorption isotherms showed Type II curves with SBET of 0.728–2.91 m2 g−1.

Keywords

• tetrakis(µ-carboxylato)diruthenium
• tetracyanidoaurate(III)
• mixed-valent Ru^IIRu^III
• crystal structure
• magnetic property
• heterometallic complex